Make a Fire Extinguisher

Did you know that fire is a chemical reaction? Fire is the most common form of a combustion reaction. Combustion, or burning, describes an interaction of oxygen and a fuel source that results in heat and light, usually in the form of a flame. Combustion combines the fuel source and oxygen to create an exothermic reaction, a reaction that generates heat above and beyond the heat needed to initiate the reaction.

In order to have a combustion reaction, the fuel and oxygen need a catalyst. A catalyst is something that causes or speeds up a chemical reaction without itself being altered. The catalyst for a fire is usually temperature. The fuel has to reach a certain temperature and be in the presence of oxygen before it will ignite. Because fire is an exothermic reaction, a single spark (which can reach temperatures over 2,000 degrees!) is hot enough to begin the combustion process, and the expelled heat is enough to keep the reaction going.

Without all three ingredients – fuel, oxygen, and heat – a combustion reaction is not possible. A fuel source like paper or wood, in the presence of oxygen but without heat, will not ignite all by itself. If it did, trees and papers would be constantly burning! Likewise, having fuel and heat might ignite a reaction, but without oxygen, the reaction cannot be sustained. That is the principle we will examine in this experiment.

The Experiment

Supplies: Baking soda, a shallow bowl, a tea light candle, vinegar, a lighter or match, and an adult helper.

What to do: Sprinkle some baking soda in the bottom of the bowl. Make sure you use enough to create a nice, even layer. Set the tea light in the middle of the bowl. Ask your adult helper to light the candle. Slowly and carefully pour the vinegar into the bowl, making sure not to splash or extinguish the candle as you pour. What happens to the baking soda? What happens to the candle?

What is happening: Combining vinegar and baking soda causes a chemical reaction. One of the products of that reaction is carbon dioxide, which is a heavier gas than the oxygen/nitrogen combination in the air. The carbon dioxide settles at the bottom of the bowl, displacing the oxygen surrounding your candle. Without oxygen, the reaction cannot be sustained and the flame goes out.

Links

For an overview on combustion, check out this article on Britannica Kids.

For more in-depth information, Mocomi examines different types of combustion, flames, and fuels.

To learn more about how fire extinguishers work to put out flames, the journalists at The Conversation answers questions from Curious Kids.

Orange Fizz

As demonstrated in the Make Carbon Dioxide experiment, acids and bases do not play well together. That experiment used vinegar and baking soda to create a reaction. In this experiment, the vinegar is replaced with something a little more mild (and tasty) – citric acid.

Citric acid is an acid found in citrus fruits like lemons, limes, grapefruits, and oranges, and in other fruits and vegetables like strawberries, raspberries, and tomatoes. It is a safe acid, and it’s what gives oranges, lemons, and limes their tartness. Different citrus fruits have different concentrations of citric acid. Lemons and limes have high concentrations, while oranges and grapefruits have lower concentrations. The higher the concentration of citric acid, the more sour-tasting a fruit will be. That is why lemon juice tastes sour and zingy while orange juice tastes sweet and tangy.

The Experiment

Supplies: an orange or clementine (cutie), some baking soda

What to do: Cut the orange into wedges or peel & separate into slices. Take a bite of the orange all by itself. Dip a second slice LIGHTLY into the baking soda. Take a bite. As you chew, it should start to bubble in your mouth. It might even taste like orange soda!

What is happening: Oranges and other citrus fruits contain citric acid. Baking soda is a base, the opposite of an acid. It is safe to eat but doesn’t taste very good on its own. As the citric acid and baking soda mix, it makes millions of carbon dioxide bubbles, the same gas you breathe out, and the same one that makes soda so fizzy.

Take it a step further: Try repeating this experiment using different fruits and vegetables. Compare what the flavors taste like and how fizzy the reaction is in your mouth. Did the juice fizz more or less that others you tried? Is there a relationship between how fizzy the bite with baking soda was compared to how sweet or sour the plain bite was?

Links

To see this experiment in action, head to YouTube and explore Science Fun for Everyone.

Make Carbon Dioxide

Carbon dioxide is a clear, odorless gas that occurs naturally in our environment. It is one of the most important gases on Earth because it is one of the components necessary for plant survival. Trees and plants need carbon dioxide and water to make their own food, and they give off oxygen in the process. Humans need the oxygen to breathe and many of our food sources are from plants, so with out plants, we would suffocate and starve! Just like plants take in carbon dioxide and give off oxygen, humans take in oxygen and give off carbon dioxide. This kind of mutually beneficial relationship is called symbiosis.

Chemistry is the study of different substances and how they interact. Chemical compounds fall into different categories, depending upon where they fall on the pH scale. pH stands for “potential of hydrogen,” and the pH scale measures how much hydrogen is contained within any given compound. Vinegar is an acid. Acids fall below 7 on the pH scale. They tend to have a sour taste and can cause a burning sensation in nasal passages when smelled. Acids are sticky and react with with metals. Baking soda is a base, meaning that it falls above 7 on the pH scale. Bases are generally odorless and have a bitter taste. They tend to be slippery and they react with fats and oils. Water is neutral, meaning it falls right in the middle of the pH scale at 7. When acids and bases combine, the reaction is a volatile one, but the acids and bases can balance each other out, resulting in compounds that are closer to neutral. This experiment will combine common substances to create an interaction that will produce carbon dioxide. Carbon dioxide, or CO2, is the same gas that is used to make soda fizzy, so releasing CO2 can cause bubbles!

The Experiment

Supplies: a tall glass, baking soda, vinegar, liquid dish soap, tap water, food coloring (optional).

What to do: DO THIS EXPERIMENT OUTSIDE OR IN THE SINK. Fill the glass half full of water. Add a tablespoon of baking soda and five drops of detergent. Add 2-3 drops of food coloring, if you want. Stir well to combine ingredients. Last, add a quarter cup of vinegar. What happened when the vinegar was added?

What is happening: Water has hydrogen and oxygen as its elemental building blocks. Baking soda and vinegar both have carbon, hydrogen, and oxygen, but the proportion of “ingredients” in each of these chemical compounds is different. Baking soda also has a fourth ingredient – sodium. When all the atoms from all the compounds are allowed to combine, they react violently. The bonds holding the atoms of each compound break, allowing the atoms to reorganize into new compounds. The hydrogen from the vinegar interacts with the sodium and the carbon from the baking soda and forms two new substances – sodium acetate (a salt) and carbonic acid (a liquid). Carbonic acid is highly unstable, so even as the carbonic acid is being formed, it is also breaking apart. Immediately the atomic bonds in the carbonic acid break down, resulting in liquid water and carbon dioxide gas. The gas is lighter than the water, so it moves upward through the liquid in the form of bubbles!

Links

For a more detailed discussion of this experiment, visit the Wonderopolis website.